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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Grote-Hynes theory ： ウィキペディア英語版 Grote-Hynes theory Grote-Hynes Theory (GH) is a theory of reaction rate in a solution phase. This rate theory was developed by James T. Hynes with his graduate student Richard F. Grote in 1980.〔Richard F. Grote, James T. Hynes, (1980) (The stable states picture of chemical reactions. II. Rate constants for condensed and gas phase reaction models ), J. Chem. Phys. 73,2715.〕 It is based on the Generalized Langevin Equation (GLE). This theory introduced the concept of frequency dependent friction for chemical rate processes in solution phase. Because of inclusion of the frequency dependent friction instead of constant friction, the theory successfully predicts the rate constant including where the reaction barrier is large and of high frequency, where the diffusion over the barrier starts decoupling from viscosity of the medium. This was the weakness of Kramer's rate theory, which underestimated the reaction rate having large barrier with high frequency. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Grote-Hynes theory」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.